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...using Outlook Express or Outlook (97 or 2000) 
In Outlook and Outlook Express click on the 'Tools' menu
and select 'Accounts...' or 'Services...'
(depending on how your system is set-up)
Doing this will open your accounts/services list.
The E-mail accounts you have are listed here.
You can either click on an account and edit the properties, or create a new mail account.
If you create a new account, you will taken through the process by 'the wizard'...
Creating a new account
or
Editing an account from the list
How does POP3 E-mail work?
It all started when an e-mail message (basically just a piece of text) gets sent from your account.
The e-mail is sent (uploaded) to your ISP/outgoing mail server, this is usually
the company that connects you to the web.
Your outgoing mail server then redirects it towards its target across the web. When it eventually
arrives at the recipients mail server it is stored until that user comes online and downloads their mail.
They connect to the Internet through their
ISP, then connect to their incoming mail server which sends it to the recipient.
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